Spectroscopic analysis and efficient diode-pumped 2.0μm emission in Ho(3+)/Tm(3+) codoped fluoride glass.
Identifieur interne : 000446 ( Main/Exploration ); précédent : 000445; suivant : 000447Spectroscopic analysis and efficient diode-pumped 2.0μm emission in Ho(3+)/Tm(3+) codoped fluoride glass.
Auteurs : Ying Tian [République populaire de Chine] ; Xufeng Jing ; Shiqing XuSource :
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [ 1873-3557 ] ; 2013.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Fluorides, Holmium, Thulium.
- chemistry : Glass.
- Absorption, Electronics, Energy Transfer, Kinetics, Lasers, Spectrophotometry, Infrared, Time Factors.
Abstract
Intense 2.0μm emission has been obtained in Ho(3+)/Tm(3+) codoped ZBLAY glass pumped by common laser diode. Three intensity parameters and radiative properties have been determined from the absorption spectrum based on the Judd-Ofelt theory. The 2μm emission characteristics and the energy transfer mechanism upon excitation of a conventional 800nm laser diode are investigated. Efficient Tm(3+) to Ho(3+) energy transfer processes have been observed in present glass and investigated using steady-state and time-resolved optical spectroscopy measurement. The energy transfer microscopic parameter has been calculated with the Inokuti-Hirayama and Förster-Dexter models. High quantum efficiency of 2μm emission (80.35%) and large energy transfer coefficient from Tm(3+) to Ho(3+) indicates this Ho(3+)/Tm(3+) codoped ZBLAY glass is a promising material for 2.0μm laser.
DOI: 10.1016/j.saa.2013.06.019
PubMed: 23831975
Affiliations:
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Le document en format XML
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<term>Lasers</term>
<term>Spectrophotométrie IR</term>
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<front><div type="abstract" xml:lang="en">Intense 2.0μm emission has been obtained in Ho(3+)/Tm(3+) codoped ZBLAY glass pumped by common laser diode. Three intensity parameters and radiative properties have been determined from the absorption spectrum based on the Judd-Ofelt theory. The 2μm emission characteristics and the energy transfer mechanism upon excitation of a conventional 800nm laser diode are investigated. Efficient Tm(3+) to Ho(3+) energy transfer processes have been observed in present glass and investigated using steady-state and time-resolved optical spectroscopy measurement. The energy transfer microscopic parameter has been calculated with the Inokuti-Hirayama and Förster-Dexter models. High quantum efficiency of 2μm emission (80.35%) and large energy transfer coefficient from Tm(3+) to Ho(3+) indicates this Ho(3+)/Tm(3+) codoped ZBLAY glass is a promising material for 2.0μm laser.</div>
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